Group 7 elements displacement reactions between halogens
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Observe the colour of the paper. Repeat step 2, using the iodine solution. Displacement reactions Using a plastic pipette put two drops of chlorine solution in each of three dimples in the spotting tile, as shown below. In the same way and using a clean plastic pipette for each solution, add bromine water and iodine solution to the spotting tile.
Show Fullscreen Source: Royal Society of Chemistry Using a plastic pipette, add chlorine water, bromine water and iodine solution to the dimples of a spotting tile. Add two drops of potassium chloride solution to each of the three dimples in column 1 of the tile. Observe and record any colour changes that take place. Add two drops of potassium bromide solution to each of the three dimples in column 2 of the tile. Add two drops of potassium iodide solution to each of the three dimples in column 3 of the tile.
Optional For reactions in which bromine or iodine are suspected to have formed, the reaction could be repeated with 2 cm3 of each solution in a test tube, and hexane could then be added to confirm the presence of bromine or iodine. Teaching notes A results table similar to the one below could be used for the recording of results.
It has been completed with expected observations. Colour after shaking with hydrocarbon solvent Effect on indicator paper Reaction with potassium chloride solution Reaction with potassium bromide solution Reaction with potassium iodide solution Chlorine water Aqueous layer: pale yellow-green to colourless Hydrocarbon layer: colourless to pale yellow-green Turns red then rapidly bleaches white No reaction The yellow-orange colour of bromine appears The brown colour of iodine appears Bromine water Aqueous layer: yellow-orange to colourless Hydrocarbon layer: colourless to pale yellow-orange Turns red then slowly bleaches white No reaction The colour darkens from yellow-orange to brown Iodine solution Aqueous layer: brown to colourless Hydrocarbon layer: colourless to purple The paper is stained brown No reaction No reaction No reaction The halogens are more soluble in the hydrocarbon and move to this top layer when shaken with a hydrocarbon solvent.
For chlorine and bromine the colour does not change. You might need a white background to see the colour of the chlorine solution. However, for iodine there is a colour change, from brown in water to purple in the hydrocarbon layer. Where no displacement reaction takes place between a halogen solution and a halide solution, it may be that some lightening in the colour of the solution is observed and this can be explained by the effect of dilution.
Iodine is the least soluble of the halogens in water. Polar water molecules interact with iodine molecules, altering the wavelengths of light they absorb. All three halogens react with water to produce a strong acid HX , and a weak acid HOX , which has bleaching properties and is an oxidising agent. With iodine it is so small that the acidic and bleaching properties of the solution are not seen in this experiment. In the displacement reactions chlorine displaces both bromine and iodine from their compounds and bromine displaces iodine.
That means that chlorine is a more powerful oxidising agent than either bromine or iodine. Similarly bromine is a more powerful oxidising agent than iodine. Bromine can remove electrons from iodide ions to give iodine - and the iodine can't get them back from the bromide ions formed. This all means that oxidising ability falls as you go down the Group. Explaining the trend Whenever one of these halogens is involved in oxidising something in solution, the halogen ends up as halide ions with water molecules attached to them.
Looking at all four of the common halogens: As you go down the Group, the ease with which these hydrated ions are formed falls, and so the halogens become less good as oxidising agents - less ready to take electrons from something else. The reason that the hydrated ions form less readily as you go down the Group is a fairly complicated mixture of several factors. Unfortunately, this is often over-simplified to give what is actually a faulty and misleading explanation.
We'll deal with this first before giving a proper explanation. The faulty explanation This is normally given for the trend in oxidising ability of chlorine, bromine and iodine, and goes like this: How easily the element forms its ions depends on how strongly the new electrons are attracted.
As the atoms get bigger, the new electrons find themselves further from the nucleus, and more and more screened from it by the inner electrons offsetting the effect of the greater nuclear charge. The bigger atoms are therefore less good at attracting new electrons and forming ions. That sounds reasonable! What's wrong with it? What we are describing is the trend in electron affinity as you go from chlorine to bromine to iodine. Electron affinity tends to fall as you go down the Group.
This is described in detail on another page. Note: If you haven't recently read about the electron affinities of the halogens , you ought to follow this link before you go on. Use the BACK button on your browser to return to this page. The snag comes if you try to expand the argument to include fluorine. Fluorine has a much higher tendency to form its hydrated ion than chlorine does.
That makes a nonsense of the whole argument. So, what is going wrong? The mistake is to look at only one part of a much more complicated process. The argument about atoms accepting electrons applies to isolated atoms in the gas state picking up electrons to make isolated ions - also in the gas state. That's not what we should be talking about. In reality: The halogen starts as diatomic molecules, X2 - which may be gas, liquid or solid, depending on the halogen. These have to be split apart to make individual atoms.
Those atoms each gain an electron. That's the stage of the process we've been concentrating on in the faulty explanation. The isolated ions become wrapped in water molecules to form hydrated ions.
Group 7 elements displacement reactions between halogens etn to btc exchange
GCSE Science Revision Chemistry \
Group 7 Halogens The halogens are found in group 7 of the Periodic Table and are one electron away from a full outer shell of electrons.
| Bill bodri super investing in stocks | The halogens include the elements chlorine, bromine and iodine which all behave in similar ways due to similarities in their electron configurations. Chlorine is less reactive and much more manageable, and added to water in small quantities to kill microorganisms to make it safe to drink. Iodine dissolves to give a rather purply solution. The usual explanation of this which is given to students at this level is over-simplistic and faulty. There is a lot of serious chemistry on this page. |
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| Cryptocurrency portfolio percentage | The oxidising agent the substance that is doing the oxidising is the chlorine. The reaction between bromine and potassium iodide can be explained in the same link. Chlorine will accept another electron to make an ion more readily than bromine will. This is yet another redox reaction. If you mix an alkane with a halogen and shine UV light on the mixture, the two molecules will react. |
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